Layane da Silva Corrêa, Rosana Oliveira Henriques, João Vitor Rios, Lindomar Alberto Lerin, Débora de Oliveira, Agenor Furigo. Acad. nanobioconjugates catalysed synthesis of methyl oleate by response surface methodology. Vermüle, H.H. Increasing environmental awareness has forced researchers to minimize the use of organic solvents in chemical synthesis. Learn more. Juana M. Bernal, Pedro Lozano, Eduardo García-Verdugo, M. Isabel Burguete, Gregorio Sánchez-Gómez, Gregorio López-López, Mathieu Pucheault, Michel Vaultier, Santiago V. Luis. Rhazafindralambo, H., C. Blecker, G. Lognay, M. Marlier, J.P. Wathelet, and M. Severin, Improvement of Enzymatic Synthesis Yields of Flavour Acetates: The Example of Isoamyl Acetate,Biotechnol. 16:247–250 (1994). ),Enzymes in Food Processing, 2nd edn., Academic Press, New York, 1975. Any queries (other than missing content) should be directed to the corresponding author for the article. Synthesis of propyl benzoate by solvent-free immobilized lipase-catalyzed transesterification: Optimization and kinetic modeling. Journal of Industrial and Engineering Chemistry. Akoh, and R.S. Gray, C.J., J.S. https://doi.org/10.1007/BF02523500, Over 10 million scientific documents at your fingertips, Not logged in CAS  Claon, P.A., and C.C. Abstract. Rizzi, M., P. Stylos, and M. Reuss, A Kinetic Study of Immobilized Lipase Catalyzing the Synthesis of Isoamyl Acetate by Transesterification inn-Hexane,Enzyme Microb. Swaisgood, H.E., Immobilization of Enzymes and Some Applications in the Food Industry, inEnzymes and Immobilized Cells in Biotechnology, edited by A.E. Akoh, C.C., Lipase-Catalyzed Synthesis of Partial Glyceride,Biotechnol. Reed, G. Phase-Equilibrium Measurements and Thermodynamic Modeling of CO2 + Geraniol, CO2 + Geraniol + Acetic Acid, and CO2 + Geraniol + Ethyl Acetate. The Lineweaver–Burk plots suggested a ternary complex with inhibition by ethyl acetate. Laskin, The Benjamin/Cummings Publishing Co. Inc., Menlo Park, 1985, p. 1. van Tol, J.B., J.B. Odenthal, J.A. Active biopolymers in green non-conventional media: a sustainable tool for developing clean chemical processes. Use the link below to share a full-text version of this article with your friends and colleagues. 16:835–838 (1994). 15:949–954 (1993). Philipe dos Santos, Giovani L. Zabot, M. Angela A. Meireles, Marcio A. Mazutti, Julian Martínez. Welsh, F.W., and R.E. Enzyme stability was high and steady-state conversions could be achieved that exceeded the largest conversions measured in batch stirred-tank reactors (BSTRs), which is probably due to the lower aw levels achieved in the PBR. lipase (PS) was immobilized by adsorption technique onto glass beads and tested for its ability to synthesize geranyl acetate by transesterification with acetic anhydride as the acyl donor. Number of times cited according to CrossRef: Microbial Lipases and Their Versatile Applications. Packaging ... Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others. Two immobilizedCandida antarctica lipases, SP382 and SP435, were investigated for their use in the synthesis of geranyl acetate by direct esterification. The process is green, clean, and useful to the perfume and flavour industries. Modern biocatalysis is a way to  develop clean catalytic technologies. The lipase-catalyzed synthesis of geranyl acetate in non-aqueous systems has been reported. Basheer, S., J.B. Snape, K. Mogi, and M. Nakajima, Transesterification Kinetics of Triglycerides for a Modified Lipase inn-Hexane,J. Williams, Lipase-Mediated Production of Ethyl Butyrate in Nonaqueous Systems,Enzyme Microb. Oil Chem. Phillips,Pseudomonas sp. Find more information about Crossref citation counts. Geranyl acetate prepared through lipase-catalyzed transesterification or esterification is considered as a “natural” product, thereby attracting increasing interest. Published: March 2002 Synthesis of geranyl acetate by esterification with lipase entrapped in hybrid sol-gel formed within nonwoven fabric. Akoh, Enzymatic Synthesis of Geranyl Acetate inn-Hexane withCandida antarctica Lipases,J. Akoh, Enzymatic Synthesis of Geraniol and Citronellol Esters by Direct Esterification inn-Hexane,Biotechnol. Claon, P.A., and C.C. Zaks, A., and A.M. Klibanov, Enzyme-Catalyzed Processes in Organic Solvents,Proc. Oil Chem. Langrand, G., N. Rondot, C. Triantaphylides, and J. Baratti, Short-Chain Ester Synthesis by Microbial Lipases,Biotechnol. Jian Xiong, Yajuan Huang, Hua Zhang, Liyun Hou. Oil Chem. Yields of up to 96% were obtained with 200 units (approximately 11% w/w of reactants) of enzyme. CAS  Technol. Valivety, R., P.J. Enzymatic synthesis of geranyl acetate in packed bed reactor in supercritical carbon dioxide under various pressure-temperature conditions and reactor configurations. Department of Food Science and Technology, University of Georgia, 30602-7610, Athens, Georgia, You can also search for this author in Bornscheuer, U.T., Lipase-Catalyzed Synthesis of Monoacyl-glycerols,Enzyme Microb. Am. 14:709–714 (1992). Gacesa, P., and J. Hubble (eds. Google Scholar. Food Chem. Akoh, Lipase-Catalyzed Synthesis of Terpene Esters by Transesterification inn-Hexane,Biotechnol. Increasing amounts of geraniol inhibited lipase activity, while excess acyl donor concentration enhanced ester production. Geranyl acetate is an aroma active rice volatile. Lipase,J. Solvents for sustainable chemical processes. Pseudomonas sp. Scalable Green Approach Toward Fragrant Acetates. Contact Technical Service. Enzymatic synthesis of geranyl acetate in packed bed reactor in supercritical carbon dioxide under various pressure-temperature conditions and reactor configurations. Lipase-Catalyzed Transesterification Synthesis of Geranyl Acetate in Organic Solvents and Its Kinetics. Soc. Sci. Soc. Chem. Please reconnect. 30:81–87 (1987). - 159.203.166.150. Duine, Relation of Enzymatic Reaction Rate and Hydrophobicity of the Solvent, inBiocatalysis in Non-Conventional Media, edited by J. Tramper, M.H. ),Common Fragrances and Flavor Materials, VCH Publishers, Dearfield Beach, 1985. Enzymatic synthesis of geranyl acetate by transesterification with acetic anhydride as acyl donor. Modelling and optimization of Lett. 16:354–359 (1986). Halling, and A.R. Please check your email for instructions on resetting your password. 12:581–586 (1990). 17:67–70 (1995). Nur Haziqah Che Marzuki, Fahrul Huyop, Hassan Youssef Aboul-Enein, Naji Arafat Mahat, Roswanira Abdul Wahab. This model was able to predict with reasonable accuracy the behavior of the PBR. Please note: If you switch to a different device, you may be asked to login again with only your ACS ID. Lett. Harshada M. Salvi, Manoj P. Kamble, Ganapati D. Yadav. Katchalski-Katzir, E., Medium and Biocatalytic Engineering, inBiocatalysis in Non-Conventional Media, edited by J. Tramper, M.H. 13:339–344 (1991). Laskin, The Benjamin/Cummings Publishing Co. Inc., Menlo Park, 1985, p. 149. Mutua, L.N., and C.C. Geranyl Acetate Synthesis in a Packed-Bed Reactor Catalyzed by Novozym in Supercritical Carbon Dioxide and in Supercritical Ethane, REQUIMTE/CQFB, Departamento de Química, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica, Portugal, Laboratory of Separation and Reaction Engineering, Departamento de Engenharia Química, Faculdade de Engenharia da Universidade do Porto, Rua Dr. Roberto Frias, 4200-465 Porto, Portugal, Laboratory of Separation and Reaction Engineering, Departamento de Tecnologia Química e Biológica, Instituto Politécnico de Bragança, Campus de Santa Apolónia, 5301-857 Bragança, Portugal. Journal of the American Oil Chemists’ Society PubMed Google Scholar. Get article recommendations from ACS based on references in your Mendeley library. 17:578–586 (1995). Part of Springer Nature. Natural flavor ester synthesis catalyzed by lipases. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. You have to login with your ACS ID befor you can login with your Mendeley account. Matheus von Linsingen Tavares, Wanderson R. Giacomin-Junior, Luciana Porto de Souza Vandenberghe, Walter G. Chapman. Correspondence to Amano International Enzyme Co.,Lipase PS Product Information Catalog, Troy, 1990. 70:43–46 (1993). It is one of the components of the essential oils of Daucus carota L. seeds. Mustranta, A., P. Forsell, and K. Poutanen, Applications of Immobilized Lipases to Transesterification and Esterification Reactions in Nonaqueous Systems,Enzyme Microb. Enzyme load, effect of substrate concentration, added water, temperature, time course, organic solvent, pH memory, and enzyme reuse were studied. Akoh, Lipase-Catalyzed Incorporation of Polyunsaturated Fatty Acids into Vegetable Oils,71:1277–1280 (1994). 15:1211–1216 (1993). Andréa B. Martins, Natália G. Graebin, André S.G. Lorenzoni, Roberto Fernandez-Lafuente, Marco A.Z. Oil Chem. Soc. Acta 575:156–165 (1979). Solid/gas biocatalysis for aroma production: An alternative process of white biotechnology. Chakraborti, A.K., and Gulhane, R. 2003. Claon, P.A., and C.C. In sc-ethane, where the solubility of water is lower, high steady-state conversions could be attained only by preventing the accumulation on the enzyme bed of the water produced during reaction. Am. Phillips, Terpene Ester Synthesis by Lipase-Catalyzed Transesterification,Biotechnol. Find more information about Crossref citation counts. Jongejan, and J.A. Klibanov, A.M., Enzymes That Work in Organic Solvents,Chemtech. Narang, and S.A. Barker, Immobilization of Lipase fromCandida cylindraceae and Its Use in the Synthesis of Menthol Esters by Transesterification,Enzyme Microb. Harshada M. Salvi, Manoj P. Kamble, Ganapati D. Yadav. Production of isoamyl acetate by enzymatic reactions in batch and packed bed reactors with supercritical CO 2. 42:2349–2352 (1994). Article  71:575–578 (1994). Your Mendeley pairing has expired. 7.5 Reaction Engineering of Biotransformations. Bauer, K., and D. Garbe (eds. volume 73, pages1379–1384(1996)Cite this article. Slight differences were observed for some operating regions, probably due to the influence of aw in the activity of the enzyme, which is not included in the model. Chulalaksananukul, W., J.S. Overall, 83% conversion of geraniol with 100% selectivity to geranyl acetate was obtained at a mole ratio of 1:7 of geraniol to ethyl acetate, using 12.7 g L−1 Novozyme 435 at 60 °C for 2 h. At higher concentrations of acyl donor, it was noticed that the conversion of geranyl acetate was increased. Working off-campus? Salter, G.J., and D.B. Arthur Luiz Baião Dias, Philipe dos Santos, Julian Martínez. Biophys. Akoh, Effect of Reaction Parameters on SP435 Lipase-Catalyzed Synthesis of Citronellyl Acetate in Organic Solvent,Enzyme Microb. Tanaka, A., and S. Fukui, Bioconversion of Lipophilic Compounds by Immobilized Biocatalysts in the Presence of Organic Solvents, inEnzymes and Immobilized Cells in Biotechnology, edited by A.E. Google Scholar. Biol. Adlercreutz, P., On the Importance of the Support Material for Enzymatic Synthesis in Organic Media, inBiocatalysis in Non-Conventional Media, edited by J. Tramper, M.H. Zaks, A., and A.M. Klibanov, The Effect of Water on the Enzyme Action in Organic Media,J. Lett. (ed. Biol. Parametric studies were conducted to optimize the conversion and yield. Akoh, and R.S. Microbial Enzymes: Roles and Applications in Industries. Ganapati D. Yadav, Department of Chemical Engineering, Institute of Chemical Technology, Nathalal Parekh Marg, Matunga, Mumbai, 400019, India. Soc. A direct transesterification reaction of geraniol with ethyl acetate was carried out to produce geranyl acetate in a batch reactor using different immobilized enzymes.